Glycolic acid 70% MSDS

glycolic acid 70% MSDS
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Glycolic acid 70% MSDS

Material Safety Data Sheet

 1.IDENTIFICATION OF THE SUBSTANCE

1.1 Product identifiers

Product name : Glycolic acid

1.2 Details of the supplier of the safety data sheet

Company : ZHONGLAN INDUSTRY CO.,LTD

Telephone : +86 531 82956570

Fax : +86 531 82956571

1.3Emergency telephone number

Emergency Phone # : +86 531 82956570

2.HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Skin corrosion (Category 1B)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Causes burns. Harmful if swallowed.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

 

Pictogram     

 

Signal word           Danger

Hazard statement(s)

H314                Causes severe skin burns and eye damage.

Precautionary statement(s)

P280                Wear protective gloves/ protective clothing/ eye protection/ face protection.

P305 + P351 + P338  IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

P310                Immediately call a POISON CENTER or doctor/ physician.

Supplemental Hazard  none

Statements

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)   Glycolic acid 99% -2

 

R-phrase(s)

R22               Harmful if swallowed.

R34               Causes burns.

S-phrase(s)

S26               In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39         Wear suitable protective clothing, gloves and eye/face protection.

S45               In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

2.3 Other hazards – none

3.COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms : Hydroxyacetic acid

Formula : C2H4O3

Component Classification Concentration

Glycollic acid

Content:   70%

CAS-No.  79-14-1

EC-No.    201-180-5

4.FIRST AID MEASURES

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.

Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea

4.3 Indication of any immediate medical attention and special treatment needed

no data available

5.FIRE-FIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides

5.3 Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information

no data available

6.ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Evacuate personnel to safe areas.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed

containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

7.HANDLING AND STORAGE

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end uses

no data available

8.EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

8.2 Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment

Eye/face protection

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested

and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove’s outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected

according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with

multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to

engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

9.PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance Form: Liquid

Colour: colourless

Point  67-72℃

PH: 2.33

Boiling point and boiling range: no data available

Flash point: no data available

Evaporation rate no data available

Flammability (solid, gas) no data available

Upper/lower flammability or explosive limits no data available

Vapour pressure no data available

Vapour density no data available

Water solubility very soluble in water

Partition coefficient: noctanol/ water: no data available

Autoignition temperature: no data available

Decomposition temperature: no data available

Viscosity: no data available

Explosive properties: no data available

Oxidizing properties: no data available

9.2 Other safety information

no data available

10.STABILITY AND REACTIVITY

10.1 Reactivity

no data available

10.2 Chemical stability

no data available

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

Other decomposition products – no data available

11.TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity – single exposure

no data available

Specific target organ toxicity – repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation Harmful if inhaled. Material is extremely destructive to the tissue of the

mucous membranes and upper respiratory tract.

Ingestion May be harmful if swallowed. Causes burns.

Skin May be harmful if absorbed through skin. Causes skin burns.

Eyes Causes eye burns.

Signs and Symptoms of Exposure

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea

Additional Information

RTECS: Not available

12.ECOLOGICAL INFORMATION

12.1 Toxicity

no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

no data available

12.6 Other adverse effects

no data available

13.DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging

Dispose of as unused product.

14.TRANSPORT INFORMATION

14.1 UN number

ADR/RID: 3265 IMDG: 3265 IATA: 3265

14.2 UN proper shipping name

ADR/RID: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

IMDG: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

IATA: Corrosive liquid, acidic, organic, n.o.s.

14.3 Transport hazard class(es)

ADR/RID: 8 IMDG: 8 IATA: 8

14.4 Packaging group

ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

14.6 Special precautions for user

no data available

15.REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

15.2 Chemical Safety Assessment

no data available

16.OTHER INFORMATION

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any

guarantee of the properties of the product. We shall not be held liable for any damage

resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

 

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